There are worse leagues than the E8 competition wise. Among themselves they are pretty competitive. In recent years they have been down a bit when it comes to the NCAA tournament and out of conference play in terms of wins, but I've seen some teams hang with the top tier of D3 soccer. I am not familiar with the coaching landscape but haven't heard anything negative.
Much different story in terms of academics. Lots of good schools in the league. Naz, SJF, Alfred, Hartwick, Sage, Utica etc are all very strong academically. You're pretty set in terms of post-grad opportunities.